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- W1968770016 abstract "The title compound, aquachloro{2,2′-[1,2-ethanediylbis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III),[MnCl(C16H14N2O2)(H2O)], is a neutral manganese(III) complex with a pseudo-octahedral metal centre. The equatorial plane comprises the four donor atoms of the tetradentate Schiff base ligand [Mn—O 1.886 (4) and 1.893 (4) Å, and Mn—N 1.978 (5) and 1.982 (5) Å], with a water molecule [Mn—O 2.383 (4) Å] and a Cl− ligand [Mn—Cl 2.4680 (16) Å] completing the coordination sphere. The distorted geometry is highlighted by the marked displacement of the MnIII ion out of the least-squares plane of the four Schiff base donor atoms by 0.165 (2) Å. These monomeric MnIII centres are then linked into a polymeric array via hydrogen bonds between the coordinated water molecule and the phenolic O-atom donors of an adjacent MnIII centre [O—H⋯O 2.789 (5) and 2.881 (5) Å]." @default.
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- W1968770016 date "2002-03-21" @default.
- W1968770016 modified "2023-10-18" @default.
- W1968770016 title "Aquachloro[<i>N</i>,<i>N</i>′-ethylenebis(salicylideneiminato)]manganese(III)" @default.
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- W1968770016 doi "https://doi.org/10.1107/s0108270102003529" @default.
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