Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968782313> ?p ?o ?g. }
Showing items 1 to 56 of
56
with 100 items per page.
- W1968782313 endingPage "978" @default.
- W1968782313 startingPage "978" @default.
- W1968782313 abstract "The mechanism of the isomerization of n-butenes catalyzed by a methanolic solution of Pt(II)–Sn(II) chloride complex has been studied by kinetic, mass-spectrometric and microwave-spectroscopic measurements. This isomerization proceeds in the presence of hydrogen. The initial rate of isomerization of 1-butene is of half-order with respect to hydrogen and of first-order with respect to 1-butene in the temperature range 0–20°C and total pressures up to 100 Torr. The deuterium distributions in reactants and products have been measured at 20°C in C4H8+ D2+ CH3OD systems. It was found that cis-CH2DCHCHCH3 and cis-CH3CDCHCH3 are formed from 1-C4H8 and trans-2-C4H8, respectively, and CH2CHCHDCH3 is produced from both cis- and trans-2-C4H8, and that “simple exchange reaction” of 1-C4H8 proceeds faster than the isomerizations, while those of 2-butenes scarcely occur. Double-bond migration and “simple exchange reaction” of propylene in the C3H6+ D2+ CH3OD system have been studied for comparison with those of n-butene isomerization. Hydrogen atoms in propylene exchanged with different rates depending on their positions." @default.
- W1968782313 created "2016-06-24" @default.
- W1968782313 creator A5067611536 @default.
- W1968782313 creator A5087046779 @default.
- W1968782313 creator A5087756547 @default.
- W1968782313 date "1972-01-01" @default.
- W1968782313 modified "2023-10-17" @default.
- W1968782313 title "Homogeneous catalysis by Pt(II)–Sn(II) chloride complex. Part 2.—Mechanism of the isomerization of n-butenes" @default.
- W1968782313 doi "https://doi.org/10.1039/f19726800978" @default.
- W1968782313 hasPublicationYear "1972" @default.
- W1968782313 type Work @default.
- W1968782313 sameAs 1968782313 @default.
- W1968782313 citedByCount "8" @default.
- W1968782313 crossrefType "journal-article" @default.
- W1968782313 hasAuthorship W1968782313A5067611536 @default.
- W1968782313 hasAuthorship W1968782313A5087046779 @default.
- W1968782313 hasAuthorship W1968782313A5087756547 @default.
- W1968782313 hasConcept C126661725 @default.
- W1968782313 hasConcept C147789679 @default.
- W1968782313 hasConcept C161790260 @default.
- W1968782313 hasConcept C178790620 @default.
- W1968782313 hasConcept C179104552 @default.
- W1968782313 hasConcept C185592680 @default.
- W1968782313 hasConcept C2781087020 @default.
- W1968782313 hasConcept C512968161 @default.
- W1968782313 hasConcept C75473681 @default.
- W1968782313 hasConceptScore W1968782313C126661725 @default.
- W1968782313 hasConceptScore W1968782313C147789679 @default.
- W1968782313 hasConceptScore W1968782313C161790260 @default.
- W1968782313 hasConceptScore W1968782313C178790620 @default.
- W1968782313 hasConceptScore W1968782313C179104552 @default.
- W1968782313 hasConceptScore W1968782313C185592680 @default.
- W1968782313 hasConceptScore W1968782313C2781087020 @default.
- W1968782313 hasConceptScore W1968782313C512968161 @default.
- W1968782313 hasConceptScore W1968782313C75473681 @default.
- W1968782313 hasIssue "0" @default.
- W1968782313 hasLocation W19687823131 @default.
- W1968782313 hasOpenAccess W1968782313 @default.
- W1968782313 hasPrimaryLocation W19687823131 @default.
- W1968782313 hasRelatedWork W1978401489 @default.
- W1968782313 hasRelatedWork W2058805047 @default.
- W1968782313 hasRelatedWork W2078305669 @default.
- W1968782313 hasRelatedWork W2363498292 @default.
- W1968782313 hasRelatedWork W2605206679 @default.
- W1968782313 hasRelatedWork W3004495138 @default.
- W1968782313 hasRelatedWork W3004986603 @default.
- W1968782313 hasRelatedWork W4238592385 @default.
- W1968782313 hasRelatedWork W4296668653 @default.
- W1968782313 hasRelatedWork W63129167 @default.
- W1968782313 hasVolume "68" @default.
- W1968782313 isParatext "false" @default.
- W1968782313 isRetracted "false" @default.
- W1968782313 magId "1968782313" @default.
- W1968782313 workType "article" @default.