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- W1968791315 abstract "Abstract The solubility data of a large number of complex cations and anions in water + methanol have been examined using the solvent sorting method to separate free energies of transfer for salts from water into water + methanol, Δ G t ⊖ (salt), into free energies of transfer for individual ions, Δ G t ⊖ (i), to compare with Δ G t ⊖ (i) determined earlier for simple cations and anions. Broadly, the spread of values of Δ G t ⊖ (i) for varying i is similar to that found earlier for the simple ions in water + methanol: Δ G t ⊖ (cation) ≈ 0 or G t ⊖ (anion)&>;0, with Δ G t ⊖ (cation) becoming more negative as more hydrophobic organic groups are present in the surface of the ion and Δ G t ⊖ (anion) becoming negative when such hydrophobic organic groups are present. In general, Δ G t ⊖ (X n − ) increases as n increases and −Δ G t ⊖ (M m + ) increases as m increases with similar ligands attached. The data for Δ G t ⊖ (Fe 2+ ) are re-examined, and it is concluded that, although large errors result from the only method currently available, Δ G t ⊖ (Fe 2+ )" @default.
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- W1968791315 date "1991-08-01" @default.
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- W1968791315 title "Ionic solvation in water + co-solvent mixtures" @default.
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- W1968791315 doi "https://doi.org/10.1016/0040-6031(91)80040-p" @default.
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