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- W1968814007 abstract "A new dinuclear manganese(II)–azido complex: [Mn(2,2′-dpa)(N3)2]2 1 (2,2′-dpa = 2,2′-dipicolylamine) has been synthesized solvothermally. X-ray crystallography analysis reveals that it consists of two crystallographically independent dimeric manganese moieties; each manganese(II) atom is coordinated by one 2,2′-dipicolylamine, one terminal azido ligand, and double end-on bridging azido ligands, exhibiting a slightly distorted octahedral sphere. There are extensive short contacts among dimeric manganese moieties, which extend the structure into an interesting three-dimensional supramolecular array. Magnetic determination of 1 indicates that dominant ferromagnetic interaction and weak antiferromagnetic interaction, which are ascribed to the end-on azido bridges and the short contacts, respectively, co-exist in this complex." @default.
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- W1968814007 date "2005-02-01" @default.
- W1968814007 modified "2023-09-24" @default.
- W1968814007 title "Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)–azido complex: [Mn(2,2′-dpa)(N3)2]2 (2,2′-dpa=2,2′-dipicolylamine)" @default.
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- W1968814007 doi "https://doi.org/10.1016/j.ica.2004.09.043" @default.
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