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• W1968833636 abstract "The diffusion current at a finite band electrode of length L and width W in a cell of finite width ( W ) but infinite length and depth is obtained by an integral equation method which offers a promising alternative to finite difference methods. A Laplace transform with respect to time T is applied to the original diffusion problem, resulting in a boundary value problem for the transformed current Î ( S ). This new problem appears typically as an integral equation for Î ( S ), which is then obtained and inverted numerically to yield the current I ( T ). The diffusion current at a hemicyclindrical electrode is also obtained as a check of the method, and a comparison of the currents obtained at these two electrode geometries is presented. Approximate formulae are provided which permit calculation of current (to within ca. 1%) at a band electrode at short (0 < (π DT ) 1 2 < 1.2 L ) and at long ((π DT ) 1 2 > 4.9 L ) times." @default.
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• W1968833636 date "1986-12-01" @default.
• W1968833636 modified "2023-09-26" @default.
• W1968833636 title "Diffusion current at a band electrode by an integral equation method" @default.
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• W1968833636 doi "https://doi.org/10.1016/0022-0728(86)87003-6" @default.
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