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- W1968851731 abstract "Mixtures of macrocyclic polyethers (crown ethers) and organic-phase-soluble liquid cation exchangers have been found to produce a synergistic effect in the extraction of metal ions. The synergistic effect is size selective; that is, it tends to be greatest for those ions that best fit the crown ether cavity. The mixtures of a liquid cation exchanger and a crown ether also allow metal ion extraction from common mineral-acid anion systems (NO3−, Cl−, SO42−) that would be impossible with the crown ether alone, because of the difficulty of solubilizing those anions in nonpolar solvents. This cooperation makes the use of crown ethers as size-selective coordinators available for process applications. Size selectivity of compounds such as crown ethers may thus become a useful new parameter in designing selective solvent extraction systems." @default.
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- W1968851731 date "1981-01-01" @default.
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- W1968851731 title "Crown ethers as size-selective synergists in solvent extraction systems: A new selectivity parameter" @default.
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- W1968851731 doi "https://doi.org/10.1016/0022-1902(81)80648-3" @default.
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