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• W1968886726 abstract "The reaction of bismuth amides or alkoxides with phenolic ligand precursors yields Bi complexes of aminetris(phenoxide)s, one of which was characterized by X-ray crystallography, revealing monomeric Bi units of the tetradentate NO3 ligand further associated via a symmetrical toluene bridge into a bis(bismuth)toluene inverted-sandwich complex. Synthesis of the analogous Sb complex suggests a markedly different geometric and electronic environment at the metal center, as evidenced by the solid-state molecular structure. Density functional theory calculations of the sandwich bismuth arene complex indicate the presence of a weak sigma*-2pi interaction." @default.
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• W1968886726 date "2006-07-12" @default.
• W1968886726 modified "2023-10-07" @default.
• W1968886726 title "Bis(bismuth)toluene Inverted-Sandwich Complex Supported by Aminetris(phenoxide) Ligands" @default.
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• W1968886726 doi "https://doi.org/10.1021/ic0609406" @default.
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