FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968891505> ?p ?o ?g. }

• W1968891505 endingPage "293" @default.
• W1968891505 startingPage "281" @default.
• W1968891505 abstract "Partial oxidation of methane to CO and H2at very small contact times (4.8 ms at STP) over different supported Ni-catalysts at 700 and 800°C, CH4/O2ratio in feed of 1.8 and gas space velocity of 5.2×105cm3·g−1·h−1(at STP) has been investigated. The catalysts were prepared by depositing NiO–MgO on different commercial low surface area porous catalyst carriers (obtained from M/S Norton Co., USA) consisting of refractory compounds (viz. SiO2, Al2O3, SiC, ZrO2, and HfO2) at different concentrations and having different surface properties and also prepared by depositing NiO on the catalyst carriers precoated with different alkaline and rare earth oxides (viz. MgO, CaO, SrO, BaO, Sm2O3, and Yb2O3). The catalysts have been characterized by their TPR by H2from 100 to 900°C, degree of NiO reduction, and H2chemisorption after the catalyst reduction at 900°C. The influence of support (its composition and surface properties), method of NiO and MgO deposition, support precoating agent, loadings of NiO and MgO (as support precoating agent), and calcination temperature on the conversion and selectivity has been studied. The influence of these catalyst parameters on the TPR, degree of NiO reduction, and H2chemisorption on the catalyst has also been studied. The catalyst characteristics are strongly influenced by the support (containing Al2O3and/or SiO2at higher concentrations and having higher surface area), precoating agent, loading of MgO precoat on the support, particularly at lower loadings (below 2 wt%), and also by the catalyst calcination temperature above 900°C. The catalyst prepared by depositing NiO on the commercial supports (except SA-5552 having much higher surface area) precoated with MgO (6 ± 1 wt%) and calcined at 900°C shows excellent performance in the catalytic process (at 800°C) with very high methane conversion (>91%), selectivity (>95%) and CO productivity (>13 mol·g−1·h−1, which is about two orders of magnitude higher than that obtained in steam reforming of methane). However, the conversion and selectivity are reduced drastically when the MgO loading is decreased below 2 wt%, the MgO precoat is replaced by that of SrO or BaO or when the catalyst is calcined above 1050°C." @default.
• W1968891505 created "2016-06-24" @default.
• W1968891505 creator A5028382385 @default.
• W1968891505 creator A5041762739 @default.
• W1968891505 creator A5058524555 @default.
• W1968891505 date "1997-12-01" @default.
• W1968891505 modified "2023-10-16" @default.
• W1968891505 title "Oxidative Conversion of Methane to Syngas over Nickel Supported on Commercial Low Surface Area Porous Catalyst Carriers Precoated with Alkaline and Rare Earth Oxides" @default.
• W1968891505 cites W1963576915 @default.
• W1968891505 cites W1967967489 @default.
• W1968891505 cites W1970238773 @default.
• W1968891505 cites W1972877871 @default.
• W1968891505 cites W1982134943 @default.
• W1968891505 cites W1993330565 @default.
• W1968891505 cites W1996957900 @default.
• W1968891505 cites W2006266658 @default.
• W1968891505 cites W2015925015 @default.
• W1968891505 cites W2042627852 @default.
• W1968891505 cites W2054222536 @default.
• W1968891505 cites W205473677 @default.
• W1968891505 cites W2060954670 @default.
• W1968891505 cites W2076255158 @default.
• W1968891505 cites W2086054121 @default.
• W1968891505 cites W2089400568 @default.
• W1968891505 cites W2094517385 @default.
• W1968891505 cites W2136136714 @default.
• W1968891505 doi "https://doi.org/10.1006/jcat.1997.1838" @default.
• W1968891505 hasPublicationYear "1997" @default.
• W1968891505 type Work @default.
• W1968891505 sameAs 1968891505 @default.
• W1968891505 citedByCount "124" @default.
• W1968891505 countsByYear W19688915052012 @default.
• W1968891505 countsByYear W19688915052013 @default.
• W1968891505 countsByYear W19688915052014 @default.
• W1968891505 countsByYear W19688915052015 @default.
• W1968891505 countsByYear W19688915052016 @default.
• W1968891505 countsByYear W19688915052017 @default.
• W1968891505 countsByYear W19688915052018 @default.
• W1968891505 countsByYear W19688915052019 @default.
• W1968891505 countsByYear W19688915052020 @default.
• W1968891505 countsByYear W19688915052021 @default.
• W1968891505 countsByYear W19688915052022 @default.
• W1968891505 countsByYear W19688915052023 @default.
• W1968891505 crossrefType "journal-article" @default.
• W1968891505 hasAuthorship W1968891505A5028382385 @default.
• W1968891505 hasAuthorship W1968891505A5041762739 @default.
• W1968891505 hasAuthorship W1968891505A5058524555 @default.
• W1968891505 hasConcept C118792377 @default.
• W1968891505 hasConcept C127413603 @default.
• W1968891505 hasConcept C161790260 @default.
• W1968891505 hasConcept C178394782 @default.
• W1968891505 hasConcept C178790620 @default.
• W1968891505 hasConcept C179104552 @default.
• W1968891505 hasConcept C185592680 @default.
• W1968891505 hasConcept C194439259 @default.
• W1968891505 hasConcept C2779990138 @default.
• W1968891505 hasConcept C42360764 @default.
• W1968891505 hasConcept C42922719 @default.
• W1968891505 hasConcept C504270822 @default.
• W1968891505 hasConcept C515602321 @default.
• W1968891505 hasConcept C516920438 @default.
• W1968891505 hasConcept C6648577 @default.
• W1968891505 hasConcept C7082614 @default.
• W1968891505 hasConcept C74575197 @default.
• W1968891505 hasConceptScore W1968891505C118792377 @default.
• W1968891505 hasConceptScore W1968891505C127413603 @default.
• W1968891505 hasConceptScore W1968891505C161790260 @default.
• W1968891505 hasConceptScore W1968891505C178394782 @default.
• W1968891505 hasConceptScore W1968891505C178790620 @default.
• W1968891505 hasConceptScore W1968891505C179104552 @default.
• W1968891505 hasConceptScore W1968891505C185592680 @default.
• W1968891505 hasConceptScore W1968891505C194439259 @default.
• W1968891505 hasConceptScore W1968891505C2779990138 @default.
• W1968891505 hasConceptScore W1968891505C42360764 @default.
• W1968891505 hasConceptScore W1968891505C42922719 @default.
• W1968891505 hasConceptScore W1968891505C504270822 @default.
• W1968891505 hasConceptScore W1968891505C515602321 @default.
• W1968891505 hasConceptScore W1968891505C516920438 @default.
• W1968891505 hasConceptScore W1968891505C6648577 @default.
• W1968891505 hasConceptScore W1968891505C7082614 @default.
• W1968891505 hasConceptScore W1968891505C74575197 @default.
• W1968891505 hasIssue "2" @default.
• W1968891505 hasLocation W19688915051 @default.
• W1968891505 hasOpenAccess W1968891505 @default.
• W1968891505 hasPrimaryLocation W19688915051 @default.
• W1968891505 hasRelatedWork W2008154542 @default.
• W1968891505 hasRelatedWork W2045837200 @default.
• W1968891505 hasRelatedWork W2063493867 @default.
• W1968891505 hasRelatedWork W2352337708 @default.
• W1968891505 hasRelatedWork W2360461697 @default.
• W1968891505 hasRelatedWork W2367809369 @default.
• W1968891505 hasRelatedWork W2375140982 @default.
• W1968891505 hasRelatedWork W2386580812 @default.
• W1968891505 hasRelatedWork W2887478487 @default.
• W1968891505 hasRelatedWork W4234428857 @default.
• W1968891505 hasVolume "172" @default.
• W1968891505 isParatext "false" @default.
• W1968891505 isRetracted "false" @default.

• next