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- W1968899056 abstract "Abstract The reactivity of P(III) compounds towards fluorination by Ph 3 BiF 2 was studied from the viewpoint of frontier molecular orbitals theory. The highest occupied molecular orbital (HOMO) energies of phosphites and amidophosphites were calculated. A qualitative relationship between HOMO energy levels and reactivity was found. The difference in chemical behaviour of (Me 2 N) 3 P and (Et 2 N) 3 P was attributed to steric hindrance." @default.
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- W1968899056 date "1997-12-01" @default.
- W1968899056 modified "2023-09-27" @default.
- W1968899056 title "The role of electronic and steric factors in the fluorination of P(III) compounds by Ph3BiF2" @default.
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- W1968899056 doi "https://doi.org/10.1016/s0166-1280(97)00190-5" @default.
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