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- W1968907535 abstract "Acid treatment of 3,3′,5,5′-tetrabromohydrazobenzene resulted in rearrangement (78%) accompanied by disproportionation to azo-compound and fission amine (22%). The proportions of the latter process and the rate of disappearance of the substrate were unaffected by deuteriation of the aromatic rings or by variation in the concentrationof the substrate. Similar results were obtained for the disproportionations of 4,4′-dichloro- and 4-acetylamino-substituted hydrazobenzenes. For the former, tracer experiments showed that the azo-compound was formed by oxidation of the substrate rather than by intermolecular recombination of anilino or nitrene fragments, and the percentage of such disproportionation was markedly reduced when the viscosity of the medium was increased by the addition of glycerol." @default.
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- W1968907535 date "1972-01-01" @default.
- W1968907535 modified "2023-10-18" @default.
- W1968907535 title "Mechanism of benzidine and semidine rearrangements. Part XXV. The acid-catalysed disproportionation of hydrazobenzenes" @default.
- W1968907535 doi "https://doi.org/10.1039/p29720000868" @default.
- W1968907535 hasPublicationYear "1972" @default.
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