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- W1968921381 abstract "The synthesis and spectroscopic characterization of four manganese(III) porphyrin thiolates are reported. The investigated compounds are represented by (TPP)Mn(SR), where TPP is the dianion of tetraphenylporhyrin and R is C6H5, C6H4(p-NO2), Et2NCS and C4H8NCS. Each complex was characterized by UV-vis and 1H NMR spectroscopy. The effects of axial ligands on the UV-vis spectra of synthesized manganese porphyrin complexes is discussed and proton isotropic shifts are shown to be predominantly contact in origin, reflecting extensive porphyrin-to-metal π bonding." @default.
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- W1968921381 date "1997-01-01" @default.
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- W1968921381 title "Synthesis and spectroscopic studies of manganese porphyrin-thiolate complexes" @default.
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- W1968921381 doi "https://doi.org/10.1016/s0277-5387(96)00604-3" @default.
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