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- W1968966420 abstract "Abstract Activation of molecular oxygen (1 atm, room temperature) by the nitrosyl dimer [Fe(NO)2Cl]2 in the presence of the bidentate phosphorus ligands PP (PP = 1,2-bis(diphenylphosphino)ethane, dppe, and 1,2-bis(diphenylphosphino)ethene, dppen) yields the nitrato molecular complexes Fe(NO3)2Cl(OPPO), (2), while the ionic complexes [FeCl4][Fe(NO3)2(OPPO)2], (3) are obtained when [Fe(NO)2CI]2(μ-PP) is allowed to react with molecular oxygen. Complexes 2 and 3 transfer oxygen to phosphines. They catalyze the autoxidation of cyclohexene." @default.
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- W1968966420 date "1994-06-01" @default.
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- W1968966420 title "Activation of molecular oxygen by iron nitrosyls in the presence of the bidentate phosphines 1,2-bis(diphenylphosphino)ethane and ethene" @default.
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- W1968966420 doi "https://doi.org/10.1016/0020-1693(94)03974-7" @default.
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