Matches in SemOpenAlex for { <https://semopenalex.org/work/W1968989862> ?p ?o ?g. }
- W1968989862 endingPage "185" @default.
- W1968989862 startingPage "185" @default.
- W1968989862 abstract "Ionic liquids are suitable media which stabilize charged intermediates favoring those mechanisms that occur through charge separation. We have used ionic liquids to develop a photocatalytic system to perform the reduction of a carbonyl group to alcohol, thus mimicking the behavior of the reductase enzymes. The photochemical cycle is based on the well-known electron transfer from the Ru(bpy)32+ complex in its excited state, acting as electron donor to MV2+, which acts as electron acceptor. The initial electron transfer process can be promoted upon selective Ru(bpy)32+ excitation by visible light. By means of laser flash photolysis we have provided evidence of the nature and lifetimes of the intermediates involved in the photocatalytic system. Thus, the initial electron transfer between Ru(bpy)32+ triplets and viologen MV2+ forms the MV*+ radical cation, which upon accepting an H* atom from a suitable hydrogen atom donor, forms the corresponding dihydropyridine MVH+ reducing agent." @default.
- W1968989862 created "2016-06-24" @default.
- W1968989862 creator A5014540719 @default.
- W1968989862 creator A5041532961 @default.
- W1968989862 creator A5049116279 @default.
- W1968989862 creator A5077980564 @default.
- W1968989862 creator A5082289008 @default.
- W1968989862 date "2006-01-01" @default.
- W1968989862 modified "2023-10-17" @default.
- W1968989862 title "Ionic Liquids as a Novel Medium for Photochemical Reactions. Ru(bpy)32+/ Viologen in Imidazolium Ionic Liquid as a Photocatalytic System Mimicking the Oxido-Reductase Enzyme†" @default.
- W1968989862 cites W1965402964 @default.
- W1968989862 cites W1971970902 @default.
- W1968989862 cites W1972284172 @default.
- W1968989862 cites W1997466278 @default.
- W1968989862 cites W2002260798 @default.
- W1968989862 cites W2021908094 @default.
- W1968989862 cites W2022431590 @default.
- W1968989862 cites W2029808115 @default.
- W1968989862 cites W2030789944 @default.
- W1968989862 cites W2032012867 @default.
- W1968989862 cites W2039670546 @default.
- W1968989862 cites W2042735300 @default.
- W1968989862 cites W2046202669 @default.
- W1968989862 cites W2056848872 @default.
- W1968989862 cites W2058918509 @default.
- W1968989862 cites W2060200790 @default.
- W1968989862 cites W2072209628 @default.
- W1968989862 cites W2076455204 @default.
- W1968989862 cites W2083271916 @default.
- W1968989862 cites W2084151678 @default.
- W1968989862 cites W2086492712 @default.
- W1968989862 cites W2091799999 @default.
- W1968989862 cites W2093957202 @default.
- W1968989862 cites W2103218094 @default.
- W1968989862 cites W2138219432 @default.
- W1968989862 cites W2150432047 @default.
- W1968989862 cites W2949769375 @default.
- W1968989862 cites W4248104288 @default.
- W1968989862 cites W8662325 @default.
- W1968989862 doi "https://doi.org/10.1562/2005-05-25-ra-542" @default.
- W1968989862 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16231987" @default.
- W1968989862 hasPublicationYear "2006" @default.
- W1968989862 type Work @default.
- W1968989862 sameAs 1968989862 @default.
- W1968989862 citedByCount "17" @default.
- W1968989862 countsByYear W19689898622012 @default.
- W1968989862 countsByYear W19689898622013 @default.
- W1968989862 countsByYear W19689898622015 @default.
- W1968989862 countsByYear W19689898622016 @default.
- W1968989862 countsByYear W19689898622017 @default.
- W1968989862 countsByYear W19689898622018 @default.
- W1968989862 countsByYear W19689898622019 @default.
- W1968989862 crossrefType "journal-article" @default.
- W1968989862 hasAuthorship W1968989862A5014540719 @default.
- W1968989862 hasAuthorship W1968989862A5041532961 @default.
- W1968989862 hasAuthorship W1968989862A5049116279 @default.
- W1968989862 hasAuthorship W1968989862A5077980564 @default.
- W1968989862 hasAuthorship W1968989862A5082289008 @default.
- W1968989862 hasConcept C121332964 @default.
- W1968989862 hasConcept C123669783 @default.
- W1968989862 hasConcept C13472781 @default.
- W1968989862 hasConcept C145148216 @default.
- W1968989862 hasConcept C148898269 @default.
- W1968989862 hasConcept C154881586 @default.
- W1968989862 hasConcept C161790260 @default.
- W1968989862 hasConcept C178790620 @default.
- W1968989862 hasConcept C181500209 @default.
- W1968989862 hasConcept C185544564 @default.
- W1968989862 hasConcept C185592680 @default.
- W1968989862 hasConcept C2182769 @default.
- W1968989862 hasConcept C26873012 @default.
- W1968989862 hasConcept C2776640939 @default.
- W1968989862 hasConcept C2777346182 @default.
- W1968989862 hasConcept C2778148179 @default.
- W1968989862 hasConcept C2779892579 @default.
- W1968989862 hasConcept C2780263894 @default.
- W1968989862 hasConcept C2781018080 @default.
- W1968989862 hasConcept C2900893 @default.
- W1968989862 hasConcept C54582936 @default.
- W1968989862 hasConcept C62520636 @default.
- W1968989862 hasConcept C65165184 @default.
- W1968989862 hasConcept C75473681 @default.
- W1968989862 hasConcept C93391505 @default.
- W1968989862 hasConceptScore W1968989862C121332964 @default.
- W1968989862 hasConceptScore W1968989862C123669783 @default.
- W1968989862 hasConceptScore W1968989862C13472781 @default.
- W1968989862 hasConceptScore W1968989862C145148216 @default.
- W1968989862 hasConceptScore W1968989862C148898269 @default.
- W1968989862 hasConceptScore W1968989862C154881586 @default.
- W1968989862 hasConceptScore W1968989862C161790260 @default.
- W1968989862 hasConceptScore W1968989862C178790620 @default.
- W1968989862 hasConceptScore W1968989862C181500209 @default.
- W1968989862 hasConceptScore W1968989862C185544564 @default.
- W1968989862 hasConceptScore W1968989862C185592680 @default.
- W1968989862 hasConceptScore W1968989862C2182769 @default.
- W1968989862 hasConceptScore W1968989862C26873012 @default.
- W1968989862 hasConceptScore W1968989862C2776640939 @default.
- W1968989862 hasConceptScore W1968989862C2777346182 @default.