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- W1969002509 abstract "Abstract An investigation into the molecular arrangements in Langmuir-Blodgett films of hexadecanoyltetrathiafulvalene is reported. Low-angle X-ray diffraction shows that, as deposited, the layers are organised in a simple head-to-head and tail-to-tail configuration (i.e. Y-type deposition). However, on doping with either iodine or bromine, the X-ray d-spacing is significantly reduced, implying that the molecules become interdigitated, tilted or both. The formation of a charge-transfer band for the iodine-doped multilayers is confirmed by IR spectroscopy. Experiments using X-ray photoelectron spectroscopy and UV-Vis absorption spectroscopy reveal that the semiconducting properties of these samples are probably the result of the formation of a mixed-valence charge-transfer complex." @default.
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- W1969002509 date "1990-04-01" @default.
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- W1969002509 title "Structural properties of Langmuir-Blodgett films of a long-chain tetrathiafulvalene derivative" @default.
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- W1969002509 doi "https://doi.org/10.1016/0379-6779(90)90215-7" @default.
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