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- W1969057360 abstract "The complex formation of dioxodichloromolybdenum(VI), oxotrichloromolybdenum(V) and tetrachloromolybdenum(IV) with the macrocyclic polythiaethers: 1,4,8,11-tetrathiacyclotetradecane (TTP) and 1,4,7,10,13,16-hexathiacyclooctadecane (HTO) have been studied. The new complexes [MoO2Cl2(TTP)], [(MoO2Cl2(HTO)], [(MoOCl3)2(TTP)(THF)2], [MoOCl3(TTP)], [(MoOCl3)2(HTO)], [(MoCl4)2(TTP)], [MoCl4(TTP)] and [(MoCl4)2(HTO)] were isolated. The complexes were characterized on the basis of elemental analyses, magnetic measurements, IR and mass spectra. In the given complexes the bonding mode appears to be influenced by the number of sulphur atoms, as well as the size of the ring of the investigated macrocyclic polythiaethers." @default.
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- W1969057360 date "1982-01-01" @default.
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- W1969057360 title "Complexes of Molybdenum(VI), (V) and (IV) with macrocyclic polythiaethers" @default.
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