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- W1969058975 abstract "Fixed-frequency negative-ion photoelectron spectra of tricarbonyl(η5-methylcyclopentadienyl)manganate(0), Cp*Mn(CO)3-, are obtained at 355 and 532 nm. The adiabatic electron affinity of tricarbonyl(η5-methylcyclopentadienyl)manganese(I), Cp*Mn(CO)3, as obtained from the experiments, is 0.5 ± 0.1 eV, and the vertical ionization potential of the anion is 1.0 ± 0.1 eV. By combining our electron affinity results with literature gas-phase acidity estimates for Cp*Mn(CO)3 we determine that the C−H bond dissociation energy, D[H−CH2C5H4Mn(CO)3-], in the anion is 2.2 ± 0.8 eV." @default.
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- W1969058975 date "1998-11-18" @default.
- W1969058975 modified "2023-10-12" @default.
- W1969058975 title "Negative-Ion Photoelectron Spectrum of Tricarbonyl(η<sup>5</sup>-methylcyclopentadienyl)manganate(0)" @default.
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- W1969058975 doi "https://doi.org/10.1021/jp983333f" @default.
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