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- W1969077616 abstract "Individual components of the Zeeman transitions in the rotational spectrum of H2O and D2O were resolved in fields of 25–30 kG. This allowed determination of the g values with greater accuracy than previous measurements. The g values obtained for H2O were g(523) = 0.6959 ± 0.001 and g(616) = 0.6565 ± 0.001. The g values obtained for D2O were gaa = 0.3233 ± 0.001, gbb = 0.3580 ± 0.001, and gcc = 0.3226 ± 0.001. Analysis of the combined results indicates that the g values for H2O are positive and that the values are gaa = 0.6650 ± 0.002, gbb = 0.7145 ± 0.002, and gcc = 0.6465 ± 0.002. Hyperfine structure on the 616 − 523 transition in H2O was observed in a maser spectrometer, and the spin–rotation and spin–spin coupling constants were obtained. The measured value of the rotational transition frequency was 22 235 079.85 ± 0.05 kHz. The magnetic susceptibility anisotropies and molecular quadrupole moments were determined in H2O." @default.
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- W1969077616 date "1969-05-01" @default.
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- W1969077616 title "Measurement of the Molecular g Values in H<sub>2</sub>O and D<sub>2</sub>O and Hyperfine Structure in H<sub>2</sub>O" @default.
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- W1969077616 doi "https://doi.org/10.1063/1.1671623" @default.
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