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- W1969095105 abstract "The enantioselective intramolecular addition of silyl enol ethers and silyl ketene aminals onto alkyne is described. The reaction employs DTBMSegphos−Pd(II) or Binaphane−Pd(II) complexes as catalysts for the formation of methylene cyclopentane adducts from 1,6-enyne precursors. The utility of this reaction is illustrated by its application to the total synthesis of the cytotoxic cyclolaurane-type sesquiterpene, (−)-laurebiphenyl." @default.
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- W1969095105 date "2007-02-17" @default.
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- W1969095105 title "Palladium-Catalyzed Enantioselective Cyclization of Silyloxy-1,6-Enynes" @default.
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- W1969095105 doi "https://doi.org/10.1021/ja068723r" @default.
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