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• W1969100983 abstract "Abstract Coupling nicotinoyl chloride with 3,4‐dimetoxyphenethylamine under Bischler‐Napieralski cyclization afforded the isoquinoline (4) in good yield. This latter was used as starting material to obtain with only hydrobromic acid a product with demethylation at the position 7 (5). In addition, treatment of (4) with NaBH4/MeOH gave 6,7‐dimetoxy‐1‐(pyridin‐3‐yl)‐1,2,3,4‐tetrahydroisoquinoline (6) and unexpectedly, under mild reduction of the pyridine moiety with H2/PtO2/AcOH/, gave 6,7‐dimetoxy‐1‐(piperidin‐3‐yl)‐1,2,3,4‐tetrahydroisoquinoline (7) as the title compound. The unusual chemical reactivity of 4 onto acidic conditions and catalytic hydrogenation allowed us to obtain anabaseine and anabasine derivatives under mild conditions." @default.
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• W1969100983 date "2007-04-01" @default.
• W1969100983 modified "2023-09-25" @default.
• W1969100983 title "Synthesis of Anabaseine and Anabasine Derivatives: Structural Modifications of Possible Nicotinic Agonists" @default.
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• W1969100983 doi "https://doi.org/10.1080/00397910701227168" @default.
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