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- W1969105946 abstract "Femtosecond charge-transfer dynamics in self-assembled monolayers of cyano-terminated ethane-thiolate on gold substrates was investigated with the core hole clock method. By exploiting symmetry selection rules rather than energetic selection, electrons from the nitrogen K-shell are state-selectively excited into the two symmetry-split π* orbitals of the cyano end group with X-ray photons of well-defined polarization. The charge-transfer times from these temporarily occupied orbitals to the metal substrate differ significantly. Theoretical calculations show that these two π* orbitals extend differently onto the alkane backbone and the anchoring sulfur atom, thus causing the observed dependence of the electron-transfer dynamics on the symmetry of the orbital." @default.
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- W1969105946 date "2012-01-20" @default.
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- W1969105946 title "Orbital-Symmetry-Dependent Electron Transfer through Molecules Assembled on Metal Substrates" @default.
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- W1969105946 doi "https://doi.org/10.1021/jz2015567" @default.
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