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- W1969111086 abstract "Abstract Photoemission spectra in the photon energy range 15 eV to 30 eV on clean Ir(100) show considerable dependence of spectral structure on photon energy. In addition, phtoionization cross-sections for the 4σ, 1π and 5σ levels of chemisorbed CO are strongly dependent on the polarization of the incident radiation. Finally, analysis of a broad body of published data on CO chemisorption for many metals in addition to that of this study leads to the conclusion that the separation in energy between the 4σ and 1π peaks of chemisorbed CO varies systematically with the position of the adsorbent in the Periodic Table. This is ascribed to a systematic geometrical stretching of the bonds in the adsorbate. The susceptibility of the CO molecule to discociation upon chemisorption is also found to vary systematically depending on the position of the adsorbent in the Periodic Table." @default.
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- W1969111086 date "1976-10-01" @default.
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- W1969111086 title "Synchrotron radiation study of chemisorptive bonding of CO on transition metals — Polarization effect on Ir(100)" @default.
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- W1969111086 doi "https://doi.org/10.1016/0039-6028(76)90038-8" @default.
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