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• W1969119319 endingPage "12980" @default.
• W1969119319 startingPage "12975" @default.
• W1969119319 abstract "Abstract The pnictocenium salts [Cp*PCl] + [μCl] − ( 1 a ), [Cp*PCl] + [ClAl(OR F ) 3 ] − ( 1 b ), [Cp*AsCl] + [ClAl(OR F ) 3 ] − ( 2 ), and [(Cp*) 2 P] + [μCl] − ( 3 ), in which Cp*=Me 5 C 5 , μCl=( F RO) 3 AlClAl(OR F ) 3 , and OR F =OC(CF 3 ) 3 , were prepared by halide abstraction from the respective halopnictines with the Lewis superacid PhF→Al(OR F ) 3 . 1 The X‐ray crystal structures of 1 a , 2 , and 3 established that in the half as well as in the sandwich cations the Cp* rings are attached in an η 2 ‐fashion. By using one or two equivalents of the Lewis acid, the two new weakly coordinating anions [μCl] − and [ClAl(OR F ) 3 ] − resulted. They also stabilize the highly reactive cations in PhF or 1,2‐F 2 C 6 H 4 solution at room temperature. The chloride ion affinities (CIAs) of a range of classical strong Lewis acids were also investigated. The calculations are based on a set of isodesmic BP86/SV(P) reactions and a non‐isodesmic reference reaction assessed at the G3MP2 level." @default.
• W1969119319 created "2016-06-24" @default.
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• W1969119319 date "2011-10-06" @default.
• W1969119319 modified "2023-10-18" @default.
• W1969119319 title "Facile Access to the Pnictocenium Ions [Cp*ECl]+ (E=P, As) and [(Cp*)2P]+: Chloride Ion Affinity of Al(ORF)3" @default.
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• W1969119319 doi "https://doi.org/10.1002/chem.201102077" @default.
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