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- W1969131784 abstract "A standard segment is used to determine the structural parameters r and q of the UNIQUAC combinatorial-entropy term. Generally, it is assumed that the choice of the standard segment and the influence of the absolute value of q are negligible. The standard segment area, however, does not cancel out in the model equation and, therefore, is a model parameter. In this work this parameter is determined by fitting the model to experimental data of binary n-alkane mixtures. To account for residual effects of the n-alkane mixtures, a suitable correlation was developed. From the fit a new standard segment resulted, which is about a factor of 3 smaller than the original UNIQUAC standard segment. The new standard segment significantly improves the performance of the UNIQUAC combinatorial-entropy term." @default.
- W1969131784 created "2016-06-24" @default.
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- W1969131784 date "2011-03-14" @default.
- W1969131784 modified "2023-09-23" @default.
- W1969131784 title "Improvement of the UNIQUAC Combinatorial-Entropy Term by Adjusting the Standard Segment" @default.
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- W1969131784 doi "https://doi.org/10.1021/je101132c" @default.
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