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- W1969137062 abstract "The oxidation of carbon monoxide by sulfur dioxide was studied in a single-pulse shock tube over the temperature range 1770°–2453°K. The reactant compositions were CO/SO2/Ar=1/1/98, 4/4/92, 1/4/95, and 4/1/95, with initial reactant driver (He) pressure ranges of 27–170 torr and 50–175 psi, respectively. Reflected-shock dwell times lasted 376–541 μsec. Gas-chromatographic and mass-spectrometric analyses of the shocked samples indicated that no O2, SO3, or S2O was produced and only traces of COS and CS2 were generated. Close to 2 moles of CO2, the principal product, was formed per mole of SO2 which disappeared. At the small conversions tested, precise stoichiometry could not be established, and the CO concentrations were not directly measured. Although no quantitative check on the presence of solid sulfur could be obtained, there were several qualitative indications of sulfur deposition on the shock-tube walls and on the VPC column packing. An empirical rate expression was found to beΔ(CO2)/τ=kb(Ar)0.57(CO)0.76(SO2)0.67kb=2.7×1012exp[−48,300±1,200/RT]mole−1cm3sec−1, with error limits of ±0.1 on the partial orders, and 2±0.1 for the total order. Three plausible mechanisms were considered; arguments are presented against two of these in favor of a vibrational excitation process." @default.
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- W1969137062 date "1971-01-01" @default.
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- W1969137062 title "Reaction between CO and SO2 at elevated temperatures: A shock-tube investigation" @default.
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