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• W1969155156 abstract "The current generation of polymer light-emitting electrochemical cells (LECs) suffers from insufficient stability during operation. One identified culprit is the active material, which comprises an intimate blend between an ion-conducting electrolyte and an electron-transporting conjugated polymer, as it tends to undergo phase separation during long-term operation and the intimate contact between the ion- and electron-transporting components provokes side reactions. To address these stability issues, we present here a bilayer LEC structure in which the electrolyte is spatially separated from the conjugated polymer. We demonstrate that employing this novel device structure, with its clearly separated ion- and electron-transport paths, leads to distinctly improved LEC performance in the form of decreased turn-on time and improved light emission. We also point out that it will allow for the utilization of combinations of active materials having mutually incompatible solubilities." @default.
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• W1969155156 date "2010-04-26" @default.
• W1969155156 modified "2023-10-02" @default.
• W1969155156 title "Separating Ion and Electron Transport: The Bilayer Light-Emitting Electrochemical Cell" @default.
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• W1969155156 doi "https://doi.org/10.1021/ja102038e" @default.
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