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- W1969194929 endingPage "10143" @default.
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- W1969194929 abstract "Cross-linked poly(ε-caprolactone) (PCL)-based polyesterurethane (PUR) systems have been synthesized through Diels–Alder reactions by reactive extrusion. The Diels–Alder and retro-Diels–Alder reactions proved to be useful for enhancing the molecular motion of PCL-based systems, and therefore their crystallization ability, in the design of cross-linked semicrystalline polymers with one-way and two-way shape-memory properties. Successive reactions between α,ω-diol PCL (PCL2), furfuryl alcohol, and methylene diphenyl 4,4′-diisocyanate straightforwardly afforded the α,ω-furfuryl PCL-based PUR systems, and subsequent Diels–Alder reactions with N,N-phenylenedimaleimide afforded the thermoreversible cycloadducts. The cross-linking density could be modulated by partially replacing PCL-diol with PCL-tetraol. Interestingly, the resulting PUR systems proved to be semicrystalline cross-linked polymers, the melting temperature of which (close to 45 °C) represented the switching temperature for their shape-memory properties. Qualitative and quantitative measurements demonstrated that these PUR systems exhibited one-way and two-way shape-memory properties depending on their cross-linking density." @default.
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- W1969194929 date "2011-07-08" @default.
- W1969194929 modified "2023-10-16" @default.
- W1969194929 title "Design of Cross-Linked Semicrystalline Poly(ε-caprolactone)-Based Networks with One-Way and Two-Way Shape-Memory Properties through Diels-Alder Reactions" @default.
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- W1969194929 doi "https://doi.org/10.1002/chem.201100496" @default.
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