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- W1969198523 abstract "Abstract Volumes of activation have been measured for the alkaline decomposition of triphenylbenzylphosphonium and triphenyl(p-nitrobenzyl)phosphonium ions which lead to the formation of triphenylphosphine oxide and the toluene. The rates of reaction are very strongly retarded by pressure, volumes of activation are +32 cm 3 mol −1 while the volume of reaction is +16. This accords with a two- or three-step mechanism, involving desolvation and fragmentation each of which contributes an increase in volume. Diethyl(p-nitro- phenylphosphate hydrolyses by a B Ac 2 mechanism, Δ V ne -16." @default.
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- W1969198523 date "1986-01-01" @default.
- W1969198523 modified "2023-09-27" @default.
- W1969198523 title "Volume profiles and mechanisms for the alkaline decomposition of phosphonium salts and phosphate esters" @default.
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- W1969198523 doi "https://doi.org/10.1016/s0040-4039(00)84218-5" @default.
- W1969198523 hasPublicationYear "1986" @default.
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