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• W1969218178 endingPage "139" @default.
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• W1969218178 abstract "The complexes M(CO)3Br(DBSD-N,N′) (M  Mn or Re; DBSD = di-t-butylsulfurdiimine = tBuNSN tBu) have been prepared by reaction of M(CO)5Br with DBSD. The complexes have been characterized spectroscopically (1H-NMR, IR, UV/Vis and resonance Raman) and used as starting materials for the preparation of the metal-metal bonded complexes (CO)8MM′(DBSD-N,N′) (M,M′  Mn, Re). The structure of (CO)8Mn2(DBSD-N,N′) has been determined by X-ray crystallography. Both Mn atoms have slightly distorted octahedral geometry, and the MnMn distance (2.967 Å) is longer than that in Mn2(CO)10 (2.9038 Å). The DBSD is bonded to Mn as a chelate in its trans, trans-conformation, and the NS bond lengths and NSN bond angle are nearly the same as in W(CO)4(DBSD-N,N′). The complexes (CO)8MM′(DBSD-N,N′) are transformed thermally and photochemically, into (CO)6 MM′(μ-DBSD-N,N′:N,S,N′); during this reaction the coordination of the DBSD ligand changes from chelate to bridging. This has been established by an X-ray structural study of (CO)6Mn2(μ-DBSD-N,N′:N,S,N′). Both Mn atoms possess a distorted octahedral geometry and the MnMn distance (2.638 Å) is very short. The NS bond distances are increased from ∼ 1.60 Å in the unbridged complex to ∼ 1.70 Å in this bridged species, which contains the longest NS bond observed so far for a sulfurdiimine ligand. The mechanism of the photochemical formation of this complex is discussed." @default.
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• W1969218178 date "1993-11-01" @default.
• W1969218178 modified "2023-09-27" @default.
• W1969218178 title "Syntheses, structures, and spectroscopic properties of novel sulfurdiimine complexes; spectroscopic properties of the di-t-butylsulfurdiimine (DBSD) complexes M(CO)3Br(DBSD-N,N′) (M  Mn, Re) and X-ray structures of the metal-metal bonded compounds (CO)8Mn2(DBSD-N,N′) and (CO)6Mn2(μ-DBSD-N,N′: N, S, N′)" @default.
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• W1969218178 doi "https://doi.org/10.1016/0022-328x(93)83284-3" @default.
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