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- W1969222008 abstract "Large-order perturbation theory has been applied, for the first time, to the Stark effect for ${mathrm{H}}_{2}^{+}$, yielding the Rayleigh-Schrodinger ground-state eigenvalue (polarizability) series through twentieth order; previous expansions were limited to fourth order. The calculations were performed nonadiabatically (i.e., without invoking the Born-Oppenheimer approximation) by means of the perturbational-variational Rayleigh-Ritz formalism. The leading terms of the Rayleigh-Schrodinger polarizability series so obtained provide the most accurate values thus far determined for ${ensuremath{alpha}}_{mathrm{zz}}$ and ${ensuremath{gamma}}_{mathrm{zzzz}}$." @default.
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- W1969222008 date "1986-03-31" @default.
- W1969222008 modified "2023-09-26" @default.
- W1969222008 title "Twentieth-Order Perturbation Study of the Nondiabatic Electric Polarizabilities forH2+via the Perturbational-Variational Rayleigh-Ritz Formalism" @default.
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- W1969222008 doi "https://doi.org/10.1103/physrevlett.56.1358" @default.
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