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• W1969253318 endingPage "7017" @default.
• W1969253318 startingPage "7015" @default.
• W1969253318 abstract "Hydrothermal reactions of aluminum(III) nitrate or iron(III) nitrate with N,N-dimethylaminomethane-1,1-diphosphonic acid (H(4)L) and sodium hydroxide lead to two novel isostructural octanuclear metal phosphonate cages encapsulating two Na(I) ions, namely, [Al(8)Na(2)(HL)(2)(H(2)L)(10)(H(2)O)(6)] x 20 H(2)O (1) and [Fe(8)Na(2)(HL)(2)(H(2)L)(10)(H(2)O)(6)] x 22 H(2)O (2). The molecular structure of 1 can be viewed as a three-in-one cluster, in which a central zeolite D6R SBU lookalike aluminophosphonate cage is capped by two symmetry-related aluminophosphonate tetrahedral cages above and below and such a tetrahedral cage, being composed of four zeolite S6R SBU lookalike aluminophosphonate rings, further hexadentately traps one Na(+) ion in its cavity." @default.
• W1969253318 created "2016-06-24" @default.
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• W1969253318 date "2009-07-07" @default.
• W1969253318 modified "2023-09-27" @default.
• W1969253318 title "Octanuclear Aluminum(III) and Iron(III) Phosphonate Cages Encapsulating Two Na^I Ions" @default.
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• W1969253318 doi "https://doi.org/10.1021/ic901130a" @default.
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