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- W1969266514 abstract "Uranium dioxide can be dissolved directly in an imidazolium-based ionic liquid (IL) at room temperature with a tri-n-butylphosphate(TBP)–HNO3 complex. The dissolution process follows pseudo first-order kinetics initially. Raman spectroscopic studies show the dissolved uranyl ions are coordinated with TBP in the IL phase with a molar ratio of (UO2)2+ : TBP = 1 : 2. The dissolved uranyl species can be effectively transferred to a supercritical fluid carbon dioxide (sc-CO2) phase. No aqueous phase is formed in either the IL dissolution or the supercritical fluid extraction process. Absorption spectra of the extracted uranyl species in the sc-CO2 phase suggests the presence of a UO2(TBP)2(NO3)2 and HNO3 adduct probably of the form UO2(TBP)2(NO3)2·HNO3. The adduct dissociates in a water–dodecane trap solution during pressure reduction resulting in UO2(TBP)2(NO3)2 collected in the dodecane phase." @default.
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- W1969266514 date "2011-01-01" @default.
- W1969266514 modified "2023-10-14" @default.
- W1969266514 title "Uranium dioxide in ionic liquid with a tri-n-butylphosphate–HNO3 complex—dissolution and coordination environment" @default.
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- W1969266514 doi "https://doi.org/10.1039/c0dt01518k" @default.
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