FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969266699> ?p ?o ?g. }

• W1969266699 endingPage "8673" @default.
• W1969266699 startingPage "8664" @default.
• W1969266699 abstract "The diffusion of water in polylactide (PLA) was measured at various external water vapor activities (0–0.85) and temperatures (25, 35, 45 °C) using three separate experimental techniques: quartz spring microbalance (QSM), quartz crystal microbalance (QCM), and time-resolved Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectroscopy. Non-Fickian sorption kinetic behavior was observed with all the experimental techniques used over the observed experimental time scales, which was a result of the nonequilibrium state of the glassy polymer. Two phenomena were observed over two distinct time periods (two-stage sorption kinetics), where early time data revealed diffusion driven by a water concentration gradient and later time data revealed diffusion driven by slow polymer relaxation or swelling due to additional water ingress over time. Diffusion coefficients and relaxation time constants were determined by regressing the early time data to a Fickian model and the data over the entire observed experimental time scale to a diffusion-relaxation model, respectively. Diffusion coefficients increased with temperature, were constant with activity and concentration of water in the polymer, and were similar among all three experimental techniques. The high Deborah numbers (relaxation time/diffusion time) determined from the diffusion-relaxation model confirm the observed two-stage non-Fickian behavior." @default.
• W1969266699 created "2016-06-24" @default.
• W1969266699 creator A5004797457 @default.
• W1969266699 creator A5043648657 @default.
• W1969266699 creator A5051180466 @default.
• W1969266699 creator A5058488243 @default.
• W1969266699 date "2012-12-13" @default.
• W1969266699 modified "2023-09-27" @default.
• W1969266699 title "Non-Fickian Diffusion of Water in Polylactide" @default.
• W1969266699 cites W1984900087 @default.
• W1969266699 cites W2009896663 @default.
• W1969266699 cites W2015047890 @default.
• W1969266699 cites W2018103807 @default.
• W1969266699 cites W2019633940 @default.
• W1969266699 cites W2041482723 @default.
• W1969266699 cites W2048166352 @default.
• W1969266699 cites W2051922982 @default.
• W1969266699 cites W2054432898 @default.
• W1969266699 cites W2064197315 @default.
• W1969266699 cites W2090438881 @default.
• W1969266699 cites W2099435313 @default.
• W1969266699 cites W2114252566 @default.
• W1969266699 cites W2126419577 @default.
• W1969266699 cites W2145581976 @default.
• W1969266699 cites W2159969340 @default.
• W1969266699 cites W2168633442 @default.
• W1969266699 cites W2333150167 @default.
• W1969266699 doi "https://doi.org/10.1021/ie302342m" @default.
• W1969266699 hasPublicationYear "2012" @default.
• W1969266699 type Work @default.
• W1969266699 sameAs 1969266699 @default.
• W1969266699 citedByCount "31" @default.
• W1969266699 countsByYear W19692666992013 @default.
• W1969266699 countsByYear W19692666992014 @default.
• W1969266699 countsByYear W19692666992015 @default.
• W1969266699 countsByYear W19692666992016 @default.
• W1969266699 countsByYear W19692666992017 @default.
• W1969266699 countsByYear W19692666992018 @default.
• W1969266699 countsByYear W19692666992019 @default.
• W1969266699 countsByYear W19692666992020 @default.
• W1969266699 countsByYear W19692666992021 @default.
• W1969266699 countsByYear W19692666992022 @default.
• W1969266699 countsByYear W19692666992023 @default.
• W1969266699 crossrefType "journal-article" @default.
• W1969266699 hasAuthorship W1969266699A5004797457 @default.
• W1969266699 hasAuthorship W1969266699A5043648657 @default.
• W1969266699 hasAuthorship W1969266699A5051180466 @default.
• W1969266699 hasAuthorship W1969266699A5058488243 @default.
• W1969266699 hasConcept C113196181 @default.
• W1969266699 hasConcept C119599485 @default.
• W1969266699 hasConcept C121332964 @default.
• W1969266699 hasConcept C127413603 @default.
• W1969266699 hasConcept C147789679 @default.
• W1969266699 hasConcept C150394285 @default.
• W1969266699 hasConcept C153642686 @default.
• W1969266699 hasConcept C15744967 @default.
• W1969266699 hasConcept C178790620 @default.
• W1969266699 hasConcept C185592680 @default.
• W1969266699 hasConcept C192562407 @default.
• W1969266699 hasConcept C2776029896 @default.
• W1969266699 hasConcept C43617362 @default.
• W1969266699 hasConcept C49102809 @default.
• W1969266699 hasConcept C521977710 @default.
• W1969266699 hasConcept C53403541 @default.
• W1969266699 hasConcept C58445606 @default.
• W1969266699 hasConcept C69357855 @default.
• W1969266699 hasConcept C77805123 @default.
• W1969266699 hasConcept C81370116 @default.
• W1969266699 hasConcept C97355855 @default.
• W1969266699 hasConcept C9996572 @default.
• W1969266699 hasConceptScore W1969266699C113196181 @default.
• W1969266699 hasConceptScore W1969266699C119599485 @default.
• W1969266699 hasConceptScore W1969266699C121332964 @default.
• W1969266699 hasConceptScore W1969266699C127413603 @default.
• W1969266699 hasConceptScore W1969266699C147789679 @default.
• W1969266699 hasConceptScore W1969266699C150394285 @default.
• W1969266699 hasConceptScore W1969266699C153642686 @default.
• W1969266699 hasConceptScore W1969266699C15744967 @default.
• W1969266699 hasConceptScore W1969266699C178790620 @default.
• W1969266699 hasConceptScore W1969266699C185592680 @default.
• W1969266699 hasConceptScore W1969266699C192562407 @default.
• W1969266699 hasConceptScore W1969266699C2776029896 @default.
• W1969266699 hasConceptScore W1969266699C43617362 @default.
• W1969266699 hasConceptScore W1969266699C49102809 @default.
• W1969266699 hasConceptScore W1969266699C521977710 @default.
• W1969266699 hasConceptScore W1969266699C53403541 @default.
• W1969266699 hasConceptScore W1969266699C58445606 @default.
• W1969266699 hasConceptScore W1969266699C69357855 @default.
• W1969266699 hasConceptScore W1969266699C77805123 @default.
• W1969266699 hasConceptScore W1969266699C81370116 @default.
• W1969266699 hasConceptScore W1969266699C97355855 @default.
• W1969266699 hasConceptScore W1969266699C9996572 @default.
• W1969266699 hasIssue "26" @default.
• W1969266699 hasLocation W19692666991 @default.
• W1969266699 hasOpenAccess W1969266699 @default.
• W1969266699 hasPrimaryLocation W19692666991 @default.
• W1969266699 hasRelatedWork W1969266699 @default.
• W1969266699 hasRelatedWork W1996560765 @default.

• next