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• W1969280890 abstract "Multinuclear ((1)H, (13)C, (14)N, and (51)V) NMR spectroscopy has been used to study the reactions between the diperoxovanadate complex K(3)[OV(O(2))(2)(C(2)O(4))] x H(2)O (abbr. bpV(ox)) and ethylenediamine or diethylamine in aqueous solution. The interaction between bpV(ox) and diethylamine was very weak and no new complex was formed. However, bpV(ox) reacted with ethylenediamine giving a new product in which ethylenediamine attached to the vanadium atom via one nitrogen atom in a monodentate manner. Diffusion ordered spectroscopy (DOSY) measurements and theoretical calculations proved the formation of new product in bpV(ox) and ethylenediamine. The vanadium atoms in both [OV(O(2))(2)(C(2)O(4))](3-) and [OV(O(2))(2)(en)](-) species are six coordinated in solution state." @default.
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• W1969280890 date "2007-05-01" @default.
• W1969280890 modified "2023-09-25" @default.
• W1969280890 title "Interactions between diperoxovanadate complex and amide ligands in aqueous solution" @default.
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• W1969280890 doi "https://doi.org/10.1016/j.saa.2006.07.003" @default.
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