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- W1969309212 abstract "Examination of the infrared spectra of the probe ions NH 3 D + and NHD 3 + in ammonium dichromate confirms the existence of the lowest (T tr ~ 125 K) of the three transitions that are known, from nonspectroscopic evidence, to occur in this crystal below room temperature. Below T tr the ammonium ions are of two types, in an abundance ratio of 1:1 and both of symmetry C 1 . Above T tr the probe ion spectra are difficult to interpret in detail. The strength of the hydrogen-bonding interactions covers a wide range, as indicated by the difference between the highest and the lowest values of the isotopically isolated ND stretching frequencies at 10 K, 2392 and 2234 cm −1 ." @default.
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- W1969309212 date "1982-08-01" @default.
- W1969309212 modified "2023-09-27" @default.
- W1969309212 title "Infrared spectra of the ammonium ion in crystals. Part XII. Low-temperature transitions in ammonium dichromate, (NH4)2Cr2O7" @default.
- W1969309212 doi "https://doi.org/10.1139/v82-277" @default.
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