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- W1969397275 abstract "The cocatalytical effects of water and ethanol on the cationic polymerization of dioxolane and tetrahydrofuran were studied. The ion pair or were used for initiating the polymerization. The dependence of the polymerization rate on the concentration of cocatalyst was examined with various temperatures, concentrations of monomer, solvents (heptane, tetrachloroethane, tetrachloroethane-heptane mixtures, and 1,4-dioxane), and concentrations of initiator. The abscissa of the maximum of the reaction rate in the dependence mentioned above was the criterion for evaluation of the effect of the reaction variables. The changes observed are small; nevertheless, they prove the share of all components of the polymerizing system in establishing solvation equilibria, which determine the number and the reactivity of active centers and, in fact, the reaction rate." @default.
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- W1969397275 date "1968-03-01" @default.
- W1969397275 modified "2023-10-14" @default.
- W1969397275 title "Effect of the initiator solvation on the change in polymerization rates of dioxolane and tetrahydrofuran" @default.
- W1969397275 doi "https://doi.org/10.1002/pol.1968.150060309" @default.
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