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• W1969412683 abstract "The combination of a new high-resolution grating spectrometer and a spontaneous emission source has made it possible to measure precisely the 1 → 0, 2 → 1, and 2 → 0 transitions of 12C16O relative to the accurately known 12C16O laser lines which have been referred to pure frequency standards by Eng et al. The 1 → 0 and 2 → 0 band centers agree to within 0.0002 cm−1 with those measured relative to wavelength standards by Fourier transform spectroscopy (FTS). From a weighted simultaneous fit to the FTS-absorption, FTS-flame, our grating-emission, and microwave results, a set of calculated line positions was obtained for the 1 → 0, 2 → 1, and 2 → 0 transitions of 12C16O. The absolute accuracy of these line positions is believed to be ±0.0005 cm−1 and we propose that the lines can be used as secondary wavenumber standards in the infrared. The spontaneous emission sequences v′ → (v′ − 1) were measured for 12C16O up to v′ = 20, for 13C16O up to v′ = 11 (using a 13C-enriched sample), and for 12C18O up to v′ = 4 (in natural abundance). Internally consistent sets of Dunham coefficients were calculated from the best available data for the molecules of 12C16O, 13C16O, and 12C18O." @default.
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• W1969412683 date "1976-08-01" @default.
• W1969412683 modified "2023-09-27" @default.
• W1969412683 title "Infrared emission of 12C16O, 13C16O, and 12C18O" @default.
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• W1969412683 doi "https://doi.org/10.1016/0022-2852(76)90350-7" @default.
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