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- W1969433455 abstract "Abstract Acyclic amines 1 were obtained by a nucleophilic aromatic substitution (S N Ar) reaction and N ‐methylation followed by silane reduction. The optical resolution of C(aryl)–N(amine) bond atropisomers of amines 1 is described. We found that chiral acyclic amine 1a can be resolved by crystallization without any outside chiral source. Finally, we demonstrate the ability of chiral amines 1 as a ligand in a palladium‐catalyzed asymmetric allylic alkylation (up to 93 % ee )." @default.
- W1969433455 created "2016-06-24" @default.
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- W1969433455 date "2011-07-12" @default.
- W1969433455 modified "2023-09-30" @default.
- W1969433455 title "Atropisomerism at C-N Bonds of Acyclic Amines: Synthesis and Application to Palladium-Catalyzed Asymmetric Allylic Alkylations" @default.
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- W1969433455 doi "https://doi.org/10.1002/ejoc.201100769" @default.
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