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• W1969440183 startingPage "119" @default.
• W1969440183 abstract "Kinetics of ligand exchange reactions in the equatorial sites of [VO(L)5]2+ [L=acetonitrile, N,N-dimethylformamide (DMF), and N,N-dimethylacetamide (DMA)] have been studied by using high pressure NMR method. The values of activation volume (ΔV≠, cm3 mol−1) are −1.0±0.6 for [VO(CH3CN)5]2+, −6.8±0.4 for [VO(DMF)5]2+, and −9.7±0.9 for [VO(DMA)5]2+. On the basis of the ΔV≠ values obtained in the present and previous studies, the mechanism for the ligand exchange reactions in the equatorial sites of [VO(L)5]2+ (L=unidentate oxygen or nitrogen donor ligands) was discussed." @default.
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• W1969440183 date "1999-11-01" @default.
• W1969440183 modified "2023-09-26" @default.
• W1969440183 title "High pressure NMR studies on ligand exchange reactions in the equatorial sites of [VO(L)5]2+ (L=acetonitrile, N,N-dimethylformamide, and N,N-dimethylacetamide)" @default.
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• W1969440183 doi "https://doi.org/10.1016/s0020-1693(99)00283-2" @default.
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