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- W1969460619 abstract "Abstract Based on the vacancy mechanism of diffusion, a method is given for correlating the frequency factors and activation energies of self-diffusion in cubic metals. The activation energy is shown to be proportional to an appropriate elastic constant and the cube of the lattice parameter, both referred to 0°K. Reasonable agreement is found among the more recent self-diffusion determinations, with the proportionality constant being 0.0514 for face-centered cubic metals and 0.0695 for body-centered cubic metals. The theory also yields values for the fraction (λ) of the activation energy that goes into lattice straining during the elementary diffusion act. For face-centered cubic metals, λ is 0.64. For body-center cubic metals, λ cannot be calculated with any assurance because of inadequate data, but a tentative value is 0.84. These quantities, together with the above proportionality constants, permit the calculation of the self-diffusion coefficients as a function of temperature in cubic metals." @default.
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- W1969460619 date "1954-09-01" @default.
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- W1969460619 title "On self-diffusion in cubic metals" @default.
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- W1969460619 doi "https://doi.org/10.1016/0001-6160(54)90112-1" @default.
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