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- W1969471000 startingPage "731" @default.
- W1969471000 abstract "Gas-phase reactions of alkyl halides over the complexes of KCl and CaCl2 with dibenzo-18-crown-6 supported on silica gel exhibited high substitution to elimination ratio and relative reactivities of primary > secondary and iodide > bromide, in contrast to those over uncomplexed metal chlorides. These results together with stereochemistry and poisoning effect indicate that the complexation with crown ether enhances the nucleophilicity or basicity of metal chlorides." @default.
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- W1969471000 date "1977-07-05" @default.
- W1969471000 modified "2023-09-25" @default.
- W1969471000 title "NOVEL EFFECTS OF CROWN-ETHER COMPLEXATION ON THE HETEROGENEOUS GAS-PHASE REACTIONS OF ALKYL HALIDES OVER SILICA GEL-SUPPORTED METAL CHLORIDES" @default.
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- W1969471000 doi "https://doi.org/10.1246/cl.1977.731" @default.
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