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- W1969479963 abstract "Abstract The validity of the critical supersaturation model (CSM) for predicting mass transfer effects of nonequilibrium fog formation in thermal boundary layers is examined by comparing CSM predictions with those of a more complete application of homogeneous nucleation theory to a simple flow with molecular transport. Expressions for the nucleation kinetics and droplet growth are combined with the steady one-dimensional conservation equations and suitably transformed to allow a digital computer solution of the vaporization of a hot condensed phase into a cold gaseous medium. Using a one dimensional film model of the thermal boundary layer, predictions of boundary layer profiles and the effects of nonequilibrium fog formation are obtained and, as anticipated by the CSM, the gross effect of fog formation is to significantly enhance the steady state vaporization rate. Our numerical calculations for methyl alcohol evaporation/condensation confirm the conceptual and computational utility of the critical supersaturation model for this class of problems, provided critical supersaturation predictions are based on large volumetric nucleation rates. Consistent with our purposes, the present investigation is limited to binary gas mixtures with (i) a Lewis number of unity and (ii) both mixture constituents of equal molecular weight. Since methyl alcohol vapor-air mixtures conform well to these restrictions, and are of interest in both research and technology, illustrative numerical results are given for this system." @default.
- W1969479963 created "2016-06-24" @default.
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- W1969479963 date "1970-09-01" @default.
- W1969479963 modified "2023-09-25" @default.
- W1969479963 title "Enhancement of diffusion-limited vaporization rates by condensation within the thermal boundary layer 2. Comparison of homogeneous nucleation theory with the critical supersaturation model" @default.
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- W1969479963 doi "https://doi.org/10.1016/0017-9310(70)90176-6" @default.
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