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• W1969485536 endingPage "6669" @default.
• W1969485536 startingPage "6662" @default.
• W1969485536 abstract "Abstract The reactivity of the two diatomic congeneric systems [CO] .+ and [SiO] .+ towards methane has been investigated by means of mass spectrometry and quantum‐chemical calculations. While [CO] .+ gives rise to three different reaction channels, [SiO] .+ reacts only by hydrogen‐atom transfer (HAT) from methane under thermal conditions. A theoretical analysis of the respective HAT processes reveals two distinctly different mechanistic pathways for [CO] .+ and [SiO] .+ , and a comparison to the higher metal oxides of Group 14 emphasizes the particular role of carbon as a second‐row p element." @default.
• W1969485536 created "2016-06-24" @default.
• W1969485536 creator A5040888209 @default.
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• W1969485536 creator A5076265867 @default.
• W1969485536 creator A5082646196 @default.
• W1969485536 creator A5083322728 @default.
• W1969485536 date "2013-03-27" @default.
• W1969485536 modified "2023-10-18" @default.
• W1969485536 title "Mechanistic Aspects of Gas-Phase Hydrogen-Atom Transfer from Methane to [CO]^.+and [SiO]^.+: Why Do They Differ?" @default.
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