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- W1969516108 abstract "A series of conformationally rigid half-sandwich organoruthenium(II) complexes with the general formula [(η6-p-cymene)RuCl(L)] (where L = mono anionic 2-(naphthylazo)phenolato ligands) have been synthesized from the reaction of [{(η6-p-cymene)RuCl}2(μ-Cl)2] with a set of 2-(naphthylazo)phenolato O,N-donor ligands. All the ruthenium complexes were fully characterized by FT-IR, 1H NMR, and UV–Vis spectroscopy as well as elemental analysis. In dichloromethane solution all the metal complexes exhibits characteristic metal-to-ligand charge transfer bands (MLCT) and emission bands in the visible region. The molecular structure of one of the complexes [Ru(η6-p-cymene)(Cl)(L2)] (2) was determined by X-ray crystallography. Electrochemical data of all the ruthenium complexes show a two metal centered voltammetric responses with respect to Ag/AgCl at scan rate 100 mV s−1. Further, the complex (2) efficiently catalyzes the oxidation of a wide range of alcohols to their corresponding carbonyl compounds in the presence of N-methylmorpholine-N-oxide (NMO) up to 97%." @default.
- W1969516108 created "2016-06-24" @default.
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- W1969516108 date "2008-01-01" @default.
- W1969516108 modified "2023-09-26" @default.
- W1969516108 title "Half-sandwich para-cymene ruthenium(II) naphthylazophenolato complexes: Synthesis, molecular structure, light emission, redox behavior and catalytic oxidation properties" @default.
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- W1969516108 doi "https://doi.org/10.1016/j.poly.2007.08.037" @default.
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