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- W1969520896 abstract "A novel polyurethane iniferter synthesized from 1,1,2,2-tetraphenyl-1,2-ethane diol and toluene diisocyanate has been used to polymerize styrene through a ‘living’ radical mechanism. A rate equation (Rp∝[styrene]1·1 [polyurethane iniferter]0·93) and overall activation energy (Ea=99kJmol-1) have been deduced from the kinetic results. The molecular weight of the polystyrene increased with increasing polymerization time and conversion. When the polystyrene was post-polymerized in the presence of styrene and methyl methacrylate, a high molecular weight polystyrene and polystyrene–poly(methyl methacrylate) block copolymer were obtained, respectively. © 1997 SCI." @default.
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- W1969520896 date "1997-05-01" @default.
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- W1969520896 title "‘Living’ Radical Polymerization of Styrene Using Tetraphenylethane-based Polyurethane Iniferter" @default.
- W1969520896 doi "https://doi.org/10.1002/(sici)1097-0126(199705)43:1<13::aid-pi731>3.0.co;2-j" @default.
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