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- W1969520980 abstract "The differential reactivity of a new subtractor column packed with acid forms of porous poly(4- or 2-vinylpyridine) toward amines and alcohols in gas chromatograpy has been studied. Primary and secondary amines were quantitatively subtracted by formation of stable salts on the column, but tertiary amines were not subtracted quantitatively. The hydrosulphate form of the polymer could subtract primary and secondary alcohols, but not tert-butanol, which was dehydrated to the corresponding olefin. The hydrochloride form of the polymer had no affinity for the alcohols, except tert.-butanol, which was partially dehydrated. The application of the proposed subtractor columns was demonstrated by using a synthetic sample." @default.
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- W1969520980 date "1981-02-01" @default.
- W1969520980 modified "2023-10-14" @default.
- W1969520980 title "Porous hydrochloride and hydrosulphate forms of poly(vinylpyridine) beadsas subtractors for amines and alcohols in reaction gas chromatography" @default.
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- W1969520980 doi "https://doi.org/10.1016/s0021-9673(00)88917-7" @default.
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