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- W1969528043 abstract "Abstract η 3 -Allyl- or η 3 -methallyl-η 5 -cyclopentadienylpalladium react with hydrogensulfide at - 78 °C with selective cleavage of the cyclopentadienyl group to give the dimeric, thermolabile η 3 -allyl- or η 3 -methallylhydrogensulfidopalladium (2, 2a), which decompose above ≈ - 60 °C to palladiumsulfide and propene or isobutene. The new compounds have been characterised by 1 H NMR, IR and Raman spectroscopy. Similarly, η 3 -allyl- and η 3 - methallylhydrogensulfidoplatinum (6, 6 a) have been prepared from hydrogensulfide and η 3 -allyl- and η 3 -methallyl-?75-cyclopentadienylplatinum, respectively. From bis(??3-allyl)- or bis(?y3-methallyl)palladium and H2S rj3-allyl- or ??3-methallylhydrogensulfidopalladium (2', 2a') have been obtained and their IR spectra and physical properties found to differ from those of 2 or 2a." @default.
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- W1969528043 date "1983-05-01" @default.
- W1969528043 modified "2023-10-18" @default.
- W1969528043 title "η3-Allylmetall-Schwefel-Komplexe, IV/ η3-Allyl-hydrogensulfidopalladium- und -platin-Komplexe/ η3-Allylmetal-Sulfur Complexes, IV. η3-Allyl-hydrogensulfidopalladium and -platinum Complexes" @default.
- W1969528043 doi "https://doi.org/10.1515/znb-1983-0512" @default.
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