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• W1969533552 abstract "Abstract A surface enhancement effect was examined for the diffuse reflectance infrared spectra of structurally related compounds having a pyridine ring when a silver colloidal solution was used as the medium which induced the effect. Filter paper, which was considered to provide a favorable state of aggregation of the silver colloidal particles, was used for the preparation of the samples to be measured. It was proved experimentally that when the molecules were dissolved in the silver colloidal solution and the resulting solution was applied dropwise to filter paper, the spectra measured for the filter paper sample exhibited a surface-enhanced infrared absorption (SEIRA) effect for some samples, but not for other samples. It was speculated that the existence of an electron-donating functional group in the molecule was necessary for the realization of SEIRA in the diffuse reflectance infrared spectra. This speculation was confirmed by experiments involving other types of molecules: l -phenylalanine, m -aminophenol and p -chloroaniline." @default.
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• W1969533552 date "1999-01-01" @default.
• W1969533552 modified "2023-10-03" @default.
• W1969533552 title "Surface enhancement effect on the diffuse reflectance infrared Fourier transform spectra of compounds having a pyridine ring" @default.
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• W1969533552 doi "https://doi.org/10.1016/s0584-8547(98)00191-8" @default.
• W1969533552 hasPublicationYear "1999" @default.
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