Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969533803> ?p ?o ?g. }
- W1969533803 abstract "We have measured the dielectric relaxation of 2,2,6,6-tetramethyl-piperidine-1-oxyl (TEMPO) as a rotational probe in supercooled ortho-terphenyl (OTP). Due to the significant dipole moment of TEMPO compared with OTP, its contribution to the loss spectra can be identified already at moderate concentrations. For time scales ranging from 10 μs to 1 s, it is found that the tumbling mode of TEMPO is a true replica of the structural relaxation of OTP regarding average time constant, relaxation time dispersion, and the temperature dependence. While the present dielectric results are consistent with a decoupling of a spinning mode (about the nitroxyl dipole axis) of TEMPO from viscosity, they do not agree with the strong decoupling of the tumbling mode derived from electron spin resonance experiments." @default.
- W1969533803 created "2016-06-24" @default.
- W1969533803 creator A5022470629 @default.
- W1969533803 creator A5066675483 @default.
- W1969533803 date "2010-12-01" @default.
- W1969533803 modified "2023-10-17" @default.
- W1969533803 title "Dynamic coupling of a small rigid probe to viscous ortho-terphenyl" @default.
- W1969533803 cites W1944915281 @default.
- W1969533803 cites W1968529068 @default.
- W1969533803 cites W1970429564 @default.
- W1969533803 cites W1975586571 @default.
- W1969533803 cites W1976323431 @default.
- W1969533803 cites W1977508061 @default.
- W1969533803 cites W1988969882 @default.
- W1969533803 cites W1992755218 @default.
- W1969533803 cites W1997631050 @default.
- W1969533803 cites W2004291123 @default.
- W1969533803 cites W2010298614 @default.
- W1969533803 cites W2013133668 @default.
- W1969533803 cites W2018406465 @default.
- W1969533803 cites W2019453149 @default.
- W1969533803 cites W2019680887 @default.
- W1969533803 cites W2021299289 @default.
- W1969533803 cites W2021974163 @default.
- W1969533803 cites W2023600589 @default.
- W1969533803 cites W2026247412 @default.
- W1969533803 cites W2027923654 @default.
- W1969533803 cites W2030115462 @default.
- W1969533803 cites W2031510975 @default.
- W1969533803 cites W2041030396 @default.
- W1969533803 cites W2045137012 @default.
- W1969533803 cites W2058534458 @default.
- W1969533803 cites W2068535037 @default.
- W1969533803 cites W2071485039 @default.
- W1969533803 cites W2080911709 @default.
- W1969533803 cites W2087207378 @default.
- W1969533803 cites W2088654232 @default.
- W1969533803 cites W2090627946 @default.
- W1969533803 cites W2093108890 @default.
- W1969533803 cites W2093919954 @default.
- W1969533803 cites W2094071594 @default.
- W1969533803 cites W2158036413 @default.
- W1969533803 cites W2170797104 @default.
- W1969533803 cites W2483407058 @default.
- W1969533803 cites W4250448744 @default.
- W1969533803 doi "https://doi.org/10.1063/1.3506405" @default.
- W1969533803 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21142302" @default.
- W1969533803 hasPublicationYear "2010" @default.
- W1969533803 type Work @default.
- W1969533803 sameAs 1969533803 @default.
- W1969533803 citedByCount "7" @default.
- W1969533803 countsByYear W19695338032012 @default.
- W1969533803 countsByYear W19695338032013 @default.
- W1969533803 countsByYear W19695338032015 @default.
- W1969533803 countsByYear W19695338032016 @default.
- W1969533803 crossrefType "journal-article" @default.
- W1969533803 hasAuthorship W1969533803A5022470629 @default.
- W1969533803 hasAuthorship W1969533803A5066675483 @default.
- W1969533803 hasConcept C112964491 @default.
- W1969533803 hasConcept C121332964 @default.
- W1969533803 hasConcept C127172972 @default.
- W1969533803 hasConcept C127413603 @default.
- W1969533803 hasConcept C1276947 @default.
- W1969533803 hasConcept C133386390 @default.
- W1969533803 hasConcept C133731056 @default.
- W1969533803 hasConcept C15744967 @default.
- W1969533803 hasConcept C159985019 @default.
- W1969533803 hasConcept C173523689 @default.
- W1969533803 hasConcept C178790620 @default.
- W1969533803 hasConcept C185592680 @default.
- W1969533803 hasConcept C192562407 @default.
- W1969533803 hasConcept C205606062 @default.
- W1969533803 hasConcept C26873012 @default.
- W1969533803 hasConcept C2776029896 @default.
- W1969533803 hasConcept C2779394022 @default.
- W1969533803 hasConcept C41999313 @default.
- W1969533803 hasConcept C46141821 @default.
- W1969533803 hasConcept C4839761 @default.
- W1969533803 hasConcept C49040817 @default.
- W1969533803 hasConcept C77805123 @default.
- W1969533803 hasConcept C91066073 @default.
- W1969533803 hasConcept C97355855 @default.
- W1969533803 hasConceptScore W1969533803C112964491 @default.
- W1969533803 hasConceptScore W1969533803C121332964 @default.
- W1969533803 hasConceptScore W1969533803C127172972 @default.
- W1969533803 hasConceptScore W1969533803C127413603 @default.
- W1969533803 hasConceptScore W1969533803C1276947 @default.
- W1969533803 hasConceptScore W1969533803C133386390 @default.
- W1969533803 hasConceptScore W1969533803C133731056 @default.
- W1969533803 hasConceptScore W1969533803C15744967 @default.
- W1969533803 hasConceptScore W1969533803C159985019 @default.
- W1969533803 hasConceptScore W1969533803C173523689 @default.
- W1969533803 hasConceptScore W1969533803C178790620 @default.
- W1969533803 hasConceptScore W1969533803C185592680 @default.
- W1969533803 hasConceptScore W1969533803C192562407 @default.
- W1969533803 hasConceptScore W1969533803C205606062 @default.
- W1969533803 hasConceptScore W1969533803C26873012 @default.
- W1969533803 hasConceptScore W1969533803C2776029896 @default.
- W1969533803 hasConceptScore W1969533803C2779394022 @default.
- W1969533803 hasConceptScore W1969533803C41999313 @default.