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- W1969538143 abstract "Abstract Various thermochemical calculations require that mass spectrometric measurements provide absolute values for ratios of ion abundances. High-pressure mass spectrometric measurements normally employ a small slit between a high-pressure reaction chamber and the ion detection vacuum envelope. It is shown that the sampling of ions through a small slit depends classically on the square root of mass when flow through the slit can be characterized as molecular. Calculations that require ion intensity or abundance ratios, such as equilibrium constants or standard Gibbs energies of reaction, need to consider this mass effect. The nature of mass discrimination in high-pressure and stationary afterglow experiments has been characterized for traditional ion sampling through a thin slit and also for the various ion-diffusion processes present in these experiments. It has been shown that thermodynamic values obtained considering this effect are in better agreement with other measurements free of mass discrimination." @default.
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- W1969538143 date "2000-10-01" @default.
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- W1969538143 title "On mass discrimination in high-pressure mass spectrometry: potential errors in measurements leading to absolute ion abundances" @default.
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- W1969538143 doi "https://doi.org/10.1016/s1387-3806(00)00234-7" @default.
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