Matches in SemOpenAlex for { <https://semopenalex.org/work/W1969542640> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W1969542640 endingPage "384" @default.
- W1969542640 startingPage "367" @default.
- W1969542640 abstract "The compound Fe3(CO)9(μ2-H)(μ3-StBu) (1) reacts with PhCCPh upon photochemical activation under elimination of one CO group to give Fe3(CO)8(η2-μ2-HPhCCPh)(μ3-StBu) (2). In contrast, the thermally initiated reaction of Fe3(CO)9(μ2-Cl)(μ3-StBu) (3) with HCCPh results in fragmentation, yielding the binuclear products (4) and Fe2(CO)6(η2-μ2-H2CCPh)(μ2-StBu) (5. A simple preparative route to compounds 4 and 5 by the one-pot reaction of Fe2(CO)9 or Fe3(CO)12 respectively, with tBuSH and HCCPh is reported. The preparation, properties and structures of the products 2, 4, 5 and of the substitution derivative of 5, Fe2(CO)4(P(OMe)3)2(η2-μ2-H2CCPh)(μ2-StBu) (6) as well as of the byproducts from the one-pot synthesis, Fe2(CO)5(η2-μ3-tBuSCPh=CHCO)(μ2-StBu) (7 and (8) are discussed. The structures of compounds 2, 4, 5, 6 and 8 are best described as π-complexes of hetero-organometallic ligands." @default.
- W1969542640 created "2016-06-24" @default.
- W1969542640 creator A5070157134 @default.
- W1969542640 creator A5085104985 @default.
- W1969542640 date "1989-11-01" @default.
- W1969542640 modified "2023-10-17" @default.
- W1969542640 title "Reaktionen von dreikernigen schwefelverbrückten Carbonyleisen-Clustern mit Alkinen" @default.
- W1969542640 cites W1963585042 @default.
- W1969542640 cites W1977450392 @default.
- W1969542640 cites W1984579993 @default.
- W1969542640 cites W1994200261 @default.
- W1969542640 cites W1996101732 @default.
- W1969542640 cites W2004149668 @default.
- W1969542640 cites W2020215802 @default.
- W1969542640 cites W2035271913 @default.
- W1969542640 cites W2036311680 @default.
- W1969542640 cites W2043005805 @default.
- W1969542640 cites W2057214287 @default.
- W1969542640 cites W2063806554 @default.
- W1969542640 cites W2073231842 @default.
- W1969542640 cites W2078963758 @default.
- W1969542640 cites W2084154722 @default.
- W1969542640 cites W2091337225 @default.
- W1969542640 cites W2097961481 @default.
- W1969542640 cites W2148278945 @default.
- W1969542640 cites W2320336997 @default.
- W1969542640 cites W4211120526 @default.
- W1969542640 doi "https://doi.org/10.1016/0022-328x(89)85147-2" @default.
- W1969542640 hasPublicationYear "1989" @default.
- W1969542640 type Work @default.
- W1969542640 sameAs 1969542640 @default.
- W1969542640 citedByCount "22" @default.
- W1969542640 countsByYear W19695426402013 @default.
- W1969542640 crossrefType "journal-article" @default.
- W1969542640 hasAuthorship W1969542640A5070157134 @default.
- W1969542640 hasAuthorship W1969542640A5085104985 @default.
- W1969542640 hasConcept C155647269 @default.
- W1969542640 hasConcept C185592680 @default.
- W1969542640 hasConcept C18903297 @default.
- W1969542640 hasConcept C191015642 @default.
- W1969542640 hasConcept C71240020 @default.
- W1969542640 hasConcept C86803240 @default.
- W1969542640 hasConceptScore W1969542640C155647269 @default.
- W1969542640 hasConceptScore W1969542640C185592680 @default.
- W1969542640 hasConceptScore W1969542640C18903297 @default.
- W1969542640 hasConceptScore W1969542640C191015642 @default.
- W1969542640 hasConceptScore W1969542640C71240020 @default.
- W1969542640 hasConceptScore W1969542640C86803240 @default.
- W1969542640 hasIssue "2-3" @default.
- W1969542640 hasLocation W19695426401 @default.
- W1969542640 hasOpenAccess W1969542640 @default.
- W1969542640 hasPrimaryLocation W19695426401 @default.
- W1969542640 hasRelatedWork W1531601525 @default.
- W1969542640 hasRelatedWork W2319480705 @default.
- W1969542640 hasRelatedWork W2384464875 @default.
- W1969542640 hasRelatedWork W2606230654 @default.
- W1969542640 hasRelatedWork W2607424097 @default.
- W1969542640 hasRelatedWork W2748952813 @default.
- W1969542640 hasRelatedWork W2899084033 @default.
- W1969542640 hasRelatedWork W2948807893 @default.
- W1969542640 hasRelatedWork W4387497383 @default.
- W1969542640 hasRelatedWork W2778153218 @default.
- W1969542640 hasVolume "376" @default.
- W1969542640 isParatext "false" @default.
- W1969542640 isRetracted "false" @default.
- W1969542640 magId "1969542640" @default.
- W1969542640 workType "article" @default.